Coal, Coke and Solid Fuels

 

"COAL" is the general term for the rocks formed from the fossilised remains of fresh water plants in dense swamps or logs. When the plants died, they fell into the water where they were soon engulfed in the black, oxygen-deficient mud. Here they were protected from further decay & did not rot away. The mud itself was largely made of bacterially decomposed vegetable matter subsequent burial beneath sand or mud compressed or consolidated the planty layer, driving out water & other volatile substances. (The vegetable matter underwent a series of changes as this proceeded). The most of World's coal beds were deposited millions of years age in warm, humid regions. They have since been compressed by the weight of overburden or by earth movements to less than 1/20th of the thickness of the original deposit.

Types of Coal

Three Aspects of Oil Analysis From the view of value as fuel, the coals are classified according to the degree of change that they have undergone. With greater compression the vegetable material is reduced in volume becomes blacker, harder, more brittle and the individual plant fragments become more difficult to distinguish. Such changes are said to indicate and increase in rank. In other terms, rank refers to the MOISTURE, VOLATILE MATTER and FIXED CARBON in the coal and it increases with the proportions of FIXED CARBON present.

Normally, the Coal is of two types, Coking and Non-Coking (Anthracite, Bituminous, Sub-Bituminous and Lignite).

Anthracite
Anthracite is the highest rank coal and is characterized buy low volatile matter (always less than 10%) and high carbon content. It has a semi- metallic luster and is capable of burning without smoke. Semi- anthracite is coal midway between low volatile bituminous coal and anthracite.

Bituminous
Bituminous coal is that coal which in rank is between sub-bituminous coal and semi- anthracite. Volatile matter on dry ash free basis range from between 10% and 14% to 40% and over. Usually divided into three sub groups- low volatile medium volatile and high volatile.

Sub- Bituminous Coal
Sub- bituminous coal is the next highest coal in rank after lignite. Typical bed moisture levels are 10-20%, and calorific value also enters in to the classification scheme.

Lignite
Lignite is a low rank coal containing high moisture. Generally a coal is considered to be a lignite if it contains greater than 20% bed moisture (classification schemes for lignite are generally based on calorific value). Other characteristics of lignite are low reflectance, high volatile matter as high oxygen and low carbon and low carbon level and often the presence of some woody structure. In general the term is synonymous with brown coal.

Peat
Peat is the first stage in the conversion of vegetable matter to coal. Bed moistures are high, often greater than 75% and plant remains are clearly visible.

Ash
The inorganic residue after the incineration of coal to constant weight under standard conditions. Is less than the mineral matter because of the chemical changes occurring during incineration, with most important differences being loss of water of hydration, loss of carbon dioxide, and loss of sulphurous gases from sulphides.

Coal Terms

Fixed Carbon
A component of the proximate analysis calculated by difference, i.e., 100% less the sum of moisture, ash and volatile
matter, intended to give a indication of yield. Not to be confused with carbon in the ultimate analysis.

Fuel Ratio
A term primarily used only Japan and equal to fixed carbon divided by volatile matter.

Gross Calorific Value
The amount of heat liberated during laboratory testing when coal is combusted under standardized conditions. With the
temperature of starting materials and products being approximately 25 C. During actual combustion in boilers the gross
value is never achieved because some of the products most  importantly  water,  are lost in the  gaseous state with their
associated heat of vaporization. The maximum achievable calorific value under these conditions is the net calorific value.
Calorific values is also know as Specific Energy and the gross and net CV are known as the higher and lower heating value
in some countries.

Hardgrove Grindability Index
Indicates the relative grind ability or ease of pulverization of a coal in comparisons to coal in comparison to coals chosen as standards. High values indicate a coal easy to pulverize and low values indicate a coal hard to pulverize. Hard grove grindabilty index is rank dependent and increases as does rank, although anthracites have low hard grove grindability indices.

Inherent Moisture
Often used to indicate air dried moisture, particularly in Australia. In ASTM equivalent to bed moisture or equilibrium moisture.

Proximate Analysis
The analysis of coal or coke in term of moisture, ash, volatile matter and (by difference) fixed carbon.

Run-Of-Mine Reserve(ROM)
The quantity of coal potentially available to be delivered to a coal preparation facility or stockpile after mining. This is sometimes used synonymously with mine able reserves but will normally show an increase caused by extra unwanted stone inevitable taken in mining and moisture.

Strip Mine
An open cast mine where the overburden is removed (stripped) off from the coal using heavy equipment which expose the coal for loading operations.

Total Moisture
The moisture in the coal as sampled and removable under standard conditions.

Ultimate Analysis
The analysis of coal expressed in term of carbon, hydrogen, nitrogen, sulphur and oxygen, the analysis refers to the carbonaceous material only and hence is often expressed on a dry ash free basis or dry mineral matter free basis. Oxygen is generally estimated by difference although there are methods for its determination.

Volatile Matter
The loss is mass, less that due to moisture, when coal is heated under standard conditions and out of contact with air. This test is very empirical and results are very sensitive to operating conditions. Results obtained from different standard methods will not necessarily give the same result. The ASTM method generally gives a higher result than other methods.

Basis of Analysis

As Received (ar): includes Total Moisture (TM)
Air Dried (ad): includes Inherent Moisture (IM) only
Dry Basis (db): excludes all Moisture
Dry Ash Free (daf): excludes all Moisture & Ash

Proximate and Ultimate Analysis

Accurate results from proximate and ultimate analysis of coal, coke and biofuel are an important step in mining and processing operations. Ideally, these tests should comply with accepted international standards and be conducted under the strictest laboratory controls. BTH has the equipment and the experience to give you the results you need to ensure:

The Proximate Analysis of any coal i.e. the % content of Moisture, Ash (A),Volatile Matter (VM), Fixed Carbon (FC) also Sulphur (S) and Calorific Value (CV) can be expressed on any of the above bases.

Proximate and Ultimate Analysis conducted at Bombay Test House along with applicable standards, include:

Proximate Analysis Tests Includes
Moisture: ( IS 1350.1.2002 ASTM D3173, ISO 11722, AS1038.3,)
Sulfur : ( IS 1350 (part III) 2000, ASTM D4239, ISO 351, AS1038.6,)
Calorific Value: ( IS 1350(part II) 2000 , ASTM D5865, ISO 1928, AS1038.5)
Volatile Matter: (IS 1350.1.2002, ASTM D3175, ISO 562, AS1038.3,)
Fixed Carbon: (ASTM D5142, ISO 17246)
Ash : ( IS 1350.1.2002)

Total Moisture Inherent Moisture Calorific Value
Volatile Matter Fixed Carbon ASH

Ultimate Analysis Tests Includes: (By Using CHNSO Analyzer)
Ultimate analysis tests produce more comprehensive results than the proximate analyses. BTH uses the results from ultimate analysis tests to determine the elemental composition of the coal including MOISTURE, ASH, CARBON, HYDROGEN, NITROGEN, SULFUR, AND OXYGEN (BY DIFFERENCE). We determine each element through chemical analysis and express it as a percentage of the total mass of the original coal or coke sample.

Carbon Hydrogen Nitrogen
Sulphur Oxygen Ash Analysis

Bombay Test House (BTH) is equipped with excellent infrastructure and experts with decades of experience, in Chemical and Physical Analysis for the coal and coke industries. Proximate and Ultimate analyses are conducted in our state-of-the-art laboratories and deliver accurate ,impartial and independent results on time every time, from your samples:

  • Coal and Coke
  • Lignite
  • Briquettes
  • Wood
  • Fossil Fuels
  • Fuels and Agro wastes (Bio Mass)
  • Plant derivatives like rice husk etc.,